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Chemistry: explore STEM content (page 5 of 47) · openstem
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Chemistry
Reactions, bonding and organic chemistry on openstem — flashcards, notes, quizzes and molecule structures shared by the community. Study free, or clone into your library.
A matched pair of vacancies in an ionic lattice — one cation site and one anion site are both left empty. Because equal numbers of positive and negative ions are removed, overall electroneutrality of the crystal is preserved.
Chemistry
Chemistry · L5 · Crystal Defects and Semiconductors
In Marcus theory, which factor captures the energy cost of distorting both the electron-transfer species and the surrounding solvent to the geometry needed for transfer?
Describe electron impact (EI) ionization, and identify the species produced first — the molecular ion.1 / 10
In EI, the vaporised sample is bombarded with a high-energy electron beam (typically ~70 eV) that knocks a single electron out of a neutral molecule M, producing a radical cation M⁺• — the molecular ion. It's called a radical cation because it carries both a positive charge and an unpaired electron. Its mass-to-charge ratio, m/z, equals the compound's nominal molecular weight (since the mass lost as one electron is negligible).
Chemistry
Chemistry · L4 · Mass Spectrometry: EI Fragmentation Patterns
What happens in the first step of electrophilic addition of HX to an alkene?1 / 11
The alkene's π electrons act as the nucleophile and attack the electrophilic H of H–X, forming a new C–H bond. This leaves a positive charge (a carbocation) on the OTHER alkene carbon, while X⁻ is released as a spectator ion. This protonation step is rate-determining.
Chemistry
Chemistry · L4 · Addition and Elimination Mechanisms
Ethanoic acid has pKa ≈ 4.8; ethanol has pKa ≈ 16. Why is the carboxylic acid's O–H so much more acidic?1 / 7
Deprotonating the carboxylic acid gives a carboxylate ion (RCOO⁻) whose negative charge is delocalized by resonance over two equivalent C–O bonds. Deprotonating the alcohol gives an alkoxide (RO⁻) with the charge stuck on a single oxygen — far less stable, so the alcohol holds onto its proton much more tightly.
Distinguish a homogeneous equilibrium from a heterogeneous equilibrium.1 / 10
In a homogeneous equilibrium, every reactant and product is in the SAME phase (e.g. all gases, or all species dissolved in the same solution). In a heterogeneous equilibrium, the reactants and products span TWO OR MORE phases — commonly a solid or pure liquid coexisting with gases or with species in solution, such as CaCO₃(s) ⇌ CaO(s) + CO₂(g).
What makes cotton comfortable to wear in hot weather?1 / 11
Cotton is breathable and absorbs sweat and moisture well, so it feels cool and comfortable when it's hot — though it does wrinkle easily and takes a long time to dry.
List the six steps of the half-reaction (ion-electron) method for balancing a redox equation in ACIDIC solution.1 / 10
(1) Split the skeleton equation into an oxidation half-reaction and a reduction half-reaction. (2) Balance all atoms EXCEPT O and H in each half-reaction. (3) Balance O by adding H₂O. (4) Balance H by adding H⁺. (5) Balance charge by adding electrons (e⁻) to the more positive side. (6) Multiply each half-reaction by whatever factor makes the electrons lost equal the electrons gained, then add the two half-reactions together, cancelling anything that appears identically on both sides.
The Jablonski Diagram When a molecule absorbs a photon, an electron is promoted from the ground electronic state S₀ into some excited singlet state Sₙ (n ≥ 1) — often a higher singlet than S₁, since absorption is governed by whichever trans
Chemistry
Chemistry · L5 · Photochemistry: The Jablonski Diagram
What is electrolysis, and how is it the OPPOSITE of what a galvanic cell does?1 / 10
Electrolysis uses electrical energy from an external supply to force a non-spontaneous reaction — splitting an ionic compound into its elements. A galvanic cell runs the opposite direction: it lets a spontaneous redox reaction generate electrical energy. One converts electrical energy into chemical energy; the other converts chemical energy into electrical energy.
What makes a carbon atom a chiral (stereo)centre?1 / 11
It is bonded to four different substituent groups. Because no two of the four groups are identical, the atom cannot be superimposed on its own mirror image by any rotation.
The steady-state approximation: deriving a rate law from a mechanism A proposed mechanism often contains a reactive intermediate — a species formed by one step and consumed by another, never appearing in the overall equation. Its concentrat
What are the core assumptions of the Langmuir adsorption model?1 / 10
(i) The surface has a fixed number of adsorption sites, all identical; (ii) each site can hold at most one adsorbed molecule — strictly a monolayer, with no stacking of further molecules on top; (iii) sites are independent and non-interacting — occupying one site neither helps nor hinders adsorption at a neighbouring site.
What happens when you drop food colouring into still water and don't stir it?
AIt sinks straight to the bottom and stays thereBIt slowly spreads into tendrils until the water is evenly colouredCIt disappears completelyDNothing happens at all
Chemistry
Chemistry · L1 · Why Food Colouring Spreads Through Water