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Chemistry: explore STEM content · openstem
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Chemistry
Reactions, bonding and organic chemistry on openstem — flashcards, notes, quizzes and molecule structures shared by the community. Study free, or clone into your library.
You add NaOH dropwise to a colourless unknown cation solution and get a white precipitate. What single further test narrows down which white-precipitate cation you have?1 / 11
Add excess NaOH to a fresh portion of the sample. If the white precipitate redissolves to a colourless solution, the cation is amphoteric (Al³⁺, Zn²⁺, or Pb²⁺); if the precipitate is unchanged, it is a different, non-amphoteric white-hydroxide cation.
What oxidation number does an atom have when it is part of a free, uncombined element — for example, the Zn in solid zinc, or each O in O₂ gas?1 / 10
Zero. Any atom in a free element — whether monatomic (Zn) or a molecule of just that element (O₂, Cl₂) — has oxidation number 0. There's no other element around to shift electrons toward or away from it.
Density: How Tightly Is Matter Packed? Density tells you how much mass is squeezed into a given amount of space (volume). Two objects can be the same size but have very different densities if one has much more mass packed into it than the o
What causes a C–D bond to have a lower zero-point energy than the corresponding C–H bond?
ADeuterium has an extra electron compared to hydrogen, changing the electronic structureBDeuterium is heavier than hydrogen, so the bond vibrates more slowly, giving a lower zero-point energyCDeuterium forms a fundamentally different type of chemical bond to carbonDThe C-D bond dissociation potential-energy curve is a different shape from the C-H curve
The mole: a counting unit for atoms A dozen always means 12, no matter whether you're counting eggs or bicycles. A mole is the same idea, scaled up for atoms and molecules: it always means 6.02 × 10²³ particles — a number called Avogadro's
State the spectrochemical series ranking of common ligands from weakest to strongest field, as used to predict Δo.1 / 10
I⁻ < Br⁻ < Cl⁻ < F⁻ < H₂O < NH₃ < en < CN⁻ ≈ CO (strongest field). Roughly, this tracks σ-donor/π-acceptor character: the halides are π-donors that push t2g energy up (shrinking Δo), NH₃ and en are pure σ-donors sitting in the middle, and CN⁻/CO are strong π-acceptors that pull t2g energy down by accepting metal electron density into empty π* orbitals (back-bonding), which widens Δo.
Distinguish ionic, covalent, and metallic bonding.1 / 10
Ionic: electron transfer between metals and non-metals → electrostatic attraction between ions. Covalent: shared electron pairs between non-metals. Metallic: delocalised electron 'sea' among metal cations. Ionic and metallic are extremes; most real bonds are polar covalent.
Paint and galvanizing work well for fences and nails, but how do engineers protect something huge and expensive like a ship's hull or a pipeline?1 / 10
They scale up the same ideas and add a few more tools: mixing chromium into steel to make it self-protecting, bolting on sacrificial blocks of a more reactive metal, or plating on a thin barrier of another metal.
Gas Hiding in a Liquid A fizzy drink — soda, sparkling water, lemonade — has a gas hiding inside it. That gas is carbon dioxide, and it is dissolved right into the liquid, spread through it so evenly you can't see it at all. At the factory,
The smallest repeating three-dimensional block of a crystal lattice that, when tiled in all three directions with no gaps or overlaps, reproduces the entire crystal structure.
Chemistry
Chemistry · L4 · Solid State Chemistry — Unit Cells & Cubic Packing
Nanomaterials and quantum confinement A bulk semiconductor's band gap is fixed by its chemical composition and crystal structure — silicon's band gap is silicon's band gap, whether the sample is a millimeter or a meter across. That stops be
Chemistry
Chemistry · L5 · Nanomaterials and Quantum Confinement
Getting Metals from Ores Metals don't arrive ready to use — they have to be got out of the ground first. Exactly how depends on one thing: where the metal sits in the reactivity series. The more reactive a metal is, the more tightly it hold
What Comes Out of a Flame Every day, all sorts of fuels burn around us — a candle flame, a gas hob, a car engine. Whatever the fuel, burning always makes something. This page compares what actually comes out of the flame for several differe
Why is femtosecond time resolution necessary to directly observe bond-breaking dynamics?
AFemtosecond pulses are simply more intense than any other laser pulseBA single molecular vibration completes in roughly 10-100 femtoseconds, so only femtosecond-resolution measurements can resolve the actual atomic motion during bond breakingCFemtosecond lasers are the only lasers that can excite electronic transitionsDBond breaking always takes exactly one femtosecond regardless of the bond