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Chemistry: explore STEM content (page 37 of 47) · openstem
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Chemistry
Reactions, bonding and organic chemistry on openstem — flashcards, notes, quizzes and molecule structures shared by the community. Study free, or clone into your library.
What is the first step when raw water arrives at a treatment plant?1 / 12
Screening. The water passes through a coarse screen or mesh that catches large debris like leaves, litter, sticks, and other floating rubbish before anything else happens to it.
State the Boltzmann distribution law for two states i and j. What does it imply about the population of higher-energy states as temperature decreases?1 / 9
In thermal equilibrium at temperature T, the ratio of populations Nᵢ and Nⱼ of two states with energies Eᵢ and Eⱼ (degeneracies gᵢ, gⱼ) is:
Calorimetry calculations: measuring heat directly Hess's Law calculations combine already-known ΔH values algebraically. Calorimetry is how those ΔH values get measured in the first place — by tracking a temperature change in a known mass o
Chemistry
Chemistry · L4 · Calorimetry calculations: q = mcΔT, calorimeter types, and ΔH vs ΔU
What is a formation constant (Kf), also called a stability constant, for a complex ion?1 / 11
Kf is the equilibrium constant for a free (hydrated) metal ion combining with ligands to form a complex ion, e.g. Mⁿ⁺(aq) + xL(aq) ⇌ [MLₓ]ⁿ⁺(aq), Kf = [MLₓⁿ⁺] / ([Mⁿ⁺][L]ˣ). Formation constants are often very large (10⁶ to 10³⁵ or more), meaning that once enough ligand is present, essentially all the free metal ion converts into the complex.
Why Averages Hide the Interesting Behavior Ordinary bulk spectroscopy reports a signal averaged over an enormous population of molecules — roughly Avogadro's number of them in a typical solution sample. If different molecules in that popula
Separating Mixtures In a mixture, the substances are just mixed together — not chemically joined — so each one keeps its own properties. That means we can use those different properties to separate the mixture back into its parts. Which met
Energy in Chemical Reactions Every chemical reaction involves a change in energy, not just a change in substances. Some reactions release energy into their surroundings, and some reactions absorb energy from their surroundings. You can ofte
What is the FeMo-cofactor, and what reaction does it catalyze?1 / 9
The FeMo-cofactor is nitrogenase's active site: a [7Fe-9S-Mo-C-homocitrate] cluster with an interstitial carbide at its center. It catalyzes the reduction of atmospheric N2 to two molecules of NH3, a reaction that requires breaking the N≡N triple bond (bond energy ~941 kJ/mol) and consumes 16 ATP and 8 electrons per N2 fixed, releasing one H2 as an obligate byproduct.
The kinetic isotope effect: an experimental probe for the rate-determining step Identifying the rate-determining step of a proposed mechanism by argument alone — 'this step looks like the bottleneck' — or deriving a rate law from it algebra
Electrolysis: using electricity to force a reaction A galvanic cell takes a spontaneous redox reaction and lets it generate an electric current. Electrolysis runs the idea in reverse: it takes an electric current from an external supply and
Transition metals: multiple oxidation states and striking color Iron, copper, chromium, manganese, and the other transition metals behave differently from main-group metals like sodium, magnesium, and potassium in two easy-to-spot ways — wo
Chemistry
Chemistry · L3 · Transition metals: variable oxidation states and vivid color
Which scenario calls for a BACK titration rather than a direct titration?
ATitrating a strong acid of unknown concentration directly with a standard NaOH solution, using phenolphthaleinBFinding the % purity of powdered CaCO3 from a rock sample, which won't react cleanly or completely from a buretteCTitrating a strong base of unknown concentration directly with a standard HCl solution, using methyl orangeDAny titration performed with a burette instead of a pipette
Nuclear Chemistry: The Decay Law, Mass Defect & Binding Energy At L3 you saw radioactive decay as a halving staircase — after each half-life, whatever is left gets cut in half again. That picture is correct but incomplete: it only gives cle
Chemistry
Chemistry · L4 · Nuclear Chemistry: The Decay Law, Mass Defect & Binding Energy