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Chemistry: explore STEM content (page 38 of 47) · openstem
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Chemistry
Reactions, bonding and organic chemistry on openstem — flashcards, notes, quizzes and molecule structures shared by the community. Study free, or clone into your library.
What three structural criteria must a ring system meet to be aromatic?1 / 10
It must be cyclic, planar, and have a continuous (fully conjugated) ring of p orbitals overlapping all the way around — with the right number of π electrons to satisfy Hückel's rule. Miss any one of these (a non-planar ring, a broken conjugation path, or the wrong electron count) and the ring is not aromatic.
What Is Electronegativity? Electronegativity is a measure of how strongly an atom pulls the pair of electrons it shares in a covalent bond toward itself. Every bonded atom has some pull on the shared pair — electronegativity just says how s
Chemistry
Chemistry · L3 · Electronegativity and Bond Polarity
Define chemiluminescence, and contrast it with photoluminescence.1 / 12
Chemiluminescence is the emission of light produced when a chemical reaction releases enough energy in a single step to directly populate an electronically excited state of one of its products — no photon is ever absorbed beforehand. Photoluminescence (fluorescence/phosphorescence) instead starts by absorbing a photon to create the excited state. Both end the same way: an excited-state molecule relaxing to its ground state by emitting a photon. The difference is entirely in how the excited state is FIRST created.
What is femtochemistry, and why is the femtosecond timescale significant for chemical bonds?1 / 8
Femtochemistry is the study of chemical reaction dynamics on the femtosecond timescale (1 fs = 10⁻¹⁵ s), pioneered by Ahmed Zewail (1999 Nobel Prize in Chemistry). This timescale matters because it is comparable to the period of a single molecular vibration (roughly 10–100 fs for typical bond stretches), meaning femtosecond pulses are the only tool fast enough to directly capture the actual motion of atoms as a bond breaks or forms, rather than only the reactant and product states before and after.
Taming the randomness of chain growth Earlier polymer chemistry topics classified finished polymers by cross-link density and asked how chain structure sets bulk properties like Tg and crystallinity. This note steps back one stage further,
Chemistry
Chemistry · L5 · Controlled and Living Polymerization
What a buffer does A buffer solution resists changes in pH when small amounts of acid or base are added to it. Add a splash of acid to plain water and the pH crashes; add that same splash to a buffer and the pH barely moves. Buffers do not
What does Boyle's Law say about pressure and volume?1 / 8
At constant temperature, the pressure and volume of a fixed amount of gas are inversely proportional: squeeze the gas into a smaller space and its pressure rises by the same factor.
What must a monomer have to undergo ADDITION polymerization?1 / 6
A carbon–carbon double bond (C=C), like the one in ethene above. The double bond opens up so the monomer can bond directly to its neighbours on each side.
Chemistry
Chemistry · L3 · Addition vs Condensation Polymerization
What Is Gas Pressure, Really? A gas is made of an enormous number of tiny particles, spread far apart and moving around constantly in every direction. They are far too small and far too fast to see individually, but together they do somethi
Chemistry
Chemistry · L2 · Gas Pressure — the Particle Picture
Two Secret Inks You can write a message that is completely invisible — until you use a trick to make it appear! Here are two fun ways to do it. Lemon Juice Ink Dip a cotton swab or a toothpick into lemon juice and write your message on pape
Chemistry
Chemistry · L1 · Secret Messages with Invisible Ink
Crystal defects and semiconductors The unit-cell picture of a crystal — atoms sitting on perfectly regular lattice sites, with no gaps or extras — is an idealization. Real crystals almost always contain a small population of point defects:
Chemistry
Chemistry · L5 · Crystal Defects and Semiconductors
Enzyme catalysis follows the mechanism E + S ⇌ ES → E + P. Which approximation from the generic two-step mechanism (A ⇌ I → P) applies directly here, and to which species?1 / 12
The steady-state approximation, applied to the enzyme-substrate complex ES — exactly as you set d[I]/dt ≈ 0 for a generic intermediate I, here you set d[ES]/dt ≈ 0.