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Chemistry · L5 · Carbene Chemistry · flowchart

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by @openstemUpdated Chemistry
Carbene generated: 6 valence electrons at carbonSinglet or triplet ground state?Concerted, synchronous alkene additionStepwise radical addition via 1,3-diradical intermediateStereospecific cyclopropanation: alkene geometry retainedNon-stereospecific cyclopropanation: cis/trans mixtureSinglet: paired electrons, empty p orbitalTriplet: unpaired electrons, diradical character

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