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Chemistry: explore STEM content (page 21 of 47) · openstem
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Chemistry
Reactions, bonding and organic chemistry on openstem — flashcards, notes, quizzes and molecule structures shared by the community. Study free, or clone into your library.
What structural feature distinguishes a thermoset from a thermoplastic?
AA thermoset has longer chainsBA thermoset's chains are covalently cross-linked; a thermoplastic's are notCA thermoset is always an addition polymerDA thermoset contains no carbon
What core property of isotopes makes isotopic labeling useful as a mechanistic and tracing tool?
AIsotopes of an element have nearly identical chemistry but a distinguishable physical signal (mass, radioactivity, or spectral shift)BIsotopes of an element have completely different chemical reactivityCOnly radioactive isotopes can ever be used as tracersDIsotopic labeling always doubles the reaction rate
In the Haber process, N₂(g) + 3H₂(g) ⇌ 2NH₃(g) is exothermic. Why isn't the reaction simply run at a low temperature, where equilibrium favours more ammonia?1 / 10
Because a low temperature also makes the reaction very slow. It would take far too long to reach equilibrium to be economical — temperature isn't chosen for yield alone, it has to balance yield against how fast the plant can actually produce ammonia.
Chemistry
Chemistry · L3 · Industrial Equilibrium — Haber and Contact Processes
Define lattice energy precisely, including the direction of the process and the sign convention used here.1 / 9
Lattice energy (ΔH_lattice) is the enthalpy change when one mole of an ionic solid forms from its gaseous ions: M⁺(g) + X⁻(g) → MX(s). This process is always strongly exothermic (electrostatic attraction releases energy as the ions come together), so ΔH_lattice is a large negative number under this formation-direction convention. (Some sources define lattice energy as the reverse, lattice-breaking process, and report it as positive — always check which direction a given value refers to.)
Chemistry
Chemistry · L4 · Lattice Energy: Trends, the Born-Lande Equation, and the Kapustinskii Equation
Why does substituting deuterium (²H, D) for ordinary hydrogen (¹H) at a specific position barely change a molecule's chemistry, yet still matter for its kinetics?1 / 10
Isotopes of the same element have identical numbers of protons and electrons, so the electronic structure, bond lengths, and overall bonding potential-energy surface of a C–D bond are essentially the same as a C–H bond — the chemistry looks the same. What DOES change is the nuclear mass, and that alters how the bond vibrates, which can in turn change how easily it breaks.
Unstable Nuclei Most nuclei are stable and never change. Some are not — they have too many or too few neutrons for their number of protons, and they shed particles or energy until they settle into a more stable arrangement. This process is
ARf = distance travelled by substance ÷ distance travelled by solvent frontBRf = distance travelled by solvent front ÷ distance travelled by substanceCRf = distance travelled by substance × distance travelled by solvent frontDRf = distance travelled by substance − distance travelled by solvent front
From structure to reaction Ethanol is a small molecule — two carbons, an oxygen, and some hydrogens: When a fuel like methane burns in oxygen, it produces carbon dioxide and water. The equation is balanced — the same atoms appear on both si
Filtration separates an insoluble solid from a liquid. You pour the mixture through filter paper sitting in a funnel — the solid is trapped on the paper, and the liquid runs through. Example: separating sand from water.
AThe complex is highly unstable and decomposes almost immediatelyBAt equilibrium, almost all the Ag⁺ converts to the complex ion once NH₃ is in excessCThe reaction produces essentially no complex ion at allDKf must be numerically equal to Ksp(AgCl) for the math to work
What breaks apart a CFC molecule once it reaches the stratosphere?
AReaction with atmospheric water vapourBHigh-energy UV photolysis of the C–Cl bondCCombustion in the presence of atmospheric oxygenDCollision with ozone molecules
Chemistry
Chemistry · L4 · Atmospheric Chemistry — Ozone and the Greenhouse Effect
Back titration: when you can't titrate directly A direct titration works when the analyte is dissolved, reacts quickly and cleanly with the titrant, and gives a sharp, reliable endpoint. A back titration is what you reach for when one of th
Chemistry
Chemistry · L4 · Back Titration: The Excess-and-Subtract Method
What are the three subatomic particles in an atom, and where is each one found?1 / 9
Protons (positive charge) and neutrons (no charge) are packed together in the nucleus, the tiny, dense centre of the atom. Electrons (negative charge) are found outside the nucleus, arranged in shells at various distances from it.
Chemistry
Chemistry · L3 · Atomic Structure & Electron Shells