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Chemistry: explore STEM content (page 27 of 47) · openstem
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Chemistry
Reactions, bonding and organic chemistry on openstem — flashcards, notes, quizzes and molecule structures shared by the community. Study free, or clone into your library.
Energy Stored in Chemical Bonds You already know that an exothermic reaction releases energy and warms its surroundings, while an endothermic reaction absorbs energy and cools its surroundings. But where does that energy actually come from,
What is the van't Hoff factor i, and why does it appear in every colligative-property equation?1 / 10
i is the number of dissociated particles one formula unit of solute produces in solution. Colligative properties depend on total particle count, not solute identity, so every equation multiplies the 'per-mole' effect by i to account for solutes that split into multiple ions. Nonelectrolytes (glucose, sucrose, urea) have i = 1 — they don't dissociate.
Chemistry
Chemistry · L4 · Freezing Point Depression & Boiling Point Elevation
Why is the Haber process run at ~450°C instead of a lower temperature, which would favour a higher equilibrium yield of ammonia?
AA lower temperature would make the reaction too slow to be economicalBA lower temperature would shift the equilibrium toward the reactantsCThe iron catalyst only works above 450°CDAmmonia decomposes below 450°C
Chemistry
Chemistry · L3 · Industrial Equilibrium — Haber and Contact Processes — 5 Q
Dissolving vs. Melting Stir sugar into warm tea and it seems to vanish. Leave an ice cube on the counter and it also seems to vanish. But these two things are not the same at all. Melting Is About Heat Melting happens when a solid gets warm
What is retrosynthetic analysis, and which direction does its disconnection arrow (⇒) point?1 / 10
Retrosynthetic analysis works BACKWARDS from a target molecule toward simpler, ideally commercially available starting materials, by mentally breaking (disconnecting) bonds one at a time. The disconnection arrow ⇒ points from the more complex target to the simpler precursor(s) — the opposite direction from an actual forward reaction arrow (→), which is why the same route is drawn once backwards (planning) and once forwards (the real synthesis).
What is the lanthanide contraction, and what causes it?1 / 8
The lanthanide contraction is the steady, cumulative decrease in ionic radius across the lanthanide series (La³⁺ to Lu³⁺) as the 4f subshell fills. Each added 4f electron shields the increasing nuclear charge poorly (4f orbitals have a diffuse, multi-lobed shape with significant electron density near the nucleus and poor mutual shielding), so the effective nuclear charge felt by the outer electrons rises steadily across the series, pulling the ion's outer shell inward and shrinking its radius.
For a titration of a weak acid with a strong base, why does the equivalence point occur above pH 7?
ABecause the only species present at equivalence is the conjugate base of the weak acid, which hydrolyses water to produce OH-BBecause strong bases always produce a pH above 10 regardless of the acidCBecause the indicator used shifts the true equivalence pointDIt does not — the equivalence point is always exactly pH 7 for any acid-base titration
What does VSEPR theory say determines a molecule's shape?1 / 10
The electron pairs (bonding pairs AND lone pairs) around a central atom repel each other and arrange themselves to be as far apart as possible. The resulting positions of the ATOMS give the molecular shape.
Reversible reactions reach a moving balance Most reactions you meet early on run one way and stop. A reversible reaction, written with a ⇌ instead of a →, can run in BOTH directions at once under the same conditions: reactants turn into pro
Chemistry
Chemistry · L3 · Chemical Equilibrium & Le Chatelier's Principle
Metals and Reactivity Not all metals behave the same way. Some, like potassium and sodium, react so fast and so strongly that they must be stored under oil for safety. Others, like gold and platinum, barely react with anything at all — whic
What is a mole, and what is Avogadro's number?1 / 11
One mole is the amount of substance containing exactly 6.022 × 10²³ (Avogadro's number, Nₐ) elementary entities (atoms, molecules, ions). It links macroscopic mass to the atomic scale: 1 mol of ¹²C = 12.000 g.