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Chemistry: explore STEM content (page 15 of 47) · openstem
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Chemistry
Reactions, bonding and organic chemistry on openstem — flashcards, notes, quizzes and molecule structures shared by the community. Study free, or clone into your library.
What color is a dilute aqueous solution of Cu²⁺ (e.g. CuSO₄(aq))?1 / 12
Pale blue. The hydrated copper(II) ion, [Cu(H₂O)₆]²⁺, gives copper sulfate solutions and crystals their familiar blue color — one of the most recognisable transition-metal aqua-ion colors in the lab.
Chemistry
Chemistry · L4 · Transition Metal Chemistry in Solution
What is EDTA, and why is it described as a hexadentate ligand?1 / 10
EDTA (ethylenediaminetetraacetic acid) is a chelating ligand with six donor atoms — two nitrogen atoms (from its two amine groups) and four oxygen atoms (from its four carboxylate groups) — all of which can coordinate to a single metal ion at the same time. Because it offers six donor atoms simultaneously, EDTA is hexadentate: it wraps around a metal ion almost completely, like a claw, rather than approaching from just one side.
Combustion and Fuels Combustion is the scientific name for burning. It is a chemical reaction between a fuel and oxygen that releases heat and light — and, like all chemical changes, it makes brand-new substances that cannot easily be turne
Equal volumes of any gases, measured at the same temperature and pressure, contain equal numbers of particles (moles) — regardless of what the gas actually is. A litre of hydrogen and a litre of carbon dioxide, at the same temperature and pressure, hold exactly the same number of moles.
Chemistry
Chemistry · L3 · Avogadro's Law and Molar Gas Volume
Why does conventional free-radical polymerization typically give a broad molecular-weight distribution (high PDI)?
ABecause the monomer used is always a mixture of different structuresBBecause initiation and irreversible termination both occur randomly at scattered times throughout the reaction, so chains grow for very different lengths of timeCBecause free-radical polymerization always uses a metal catalyst that broadens PDIDBecause free-radical chains cannot propagate past a fixed maximum length
Chemistry
Chemistry · L5 · Controlled and Living Polymerization — 5 Q
Why do microreactors handle strongly exothermic reactions more safely than batch flasks?
ATheir high surface-area-to-volume ratio dissipates heat far faster, preventing thermal runawayBThey operate at lower pressure than batch reactorsCThey use less concentrated reagent solutions by designDThey cannot support exothermic reactions at all
What does the Karplus equation relate, in general terms?1 / 6
It relates the vicinal (three-bond, ³J) H–H coupling constant to the dihedral (torsion) angle θ between the two coupled C–H bonds: ³J(θ) = A cos²θ + B cosθ + C, where A, B, C are empirically fit constants. Measuring ³J therefore lets you estimate θ, and so probe 3D geometry rather than just connectivity.
What is a 'diagonal relationship' in the periodic table, and where does the best-known example sit?1 / 11
A diagonal relationship is when an element resembles the element one period down and one group to the right more than it resembles other members of its own group. The classic trio sits at the top-left of the table: lithium resembles magnesium, beryllium resembles aluminium, and boron resembles silicon.
In the complex [Cu(NH₃)₄]²⁺, what role does each NH₃ molecule play?
AA Lewis acid accepting an electron pair from copperBA Lewis base donating a lone pair to copperCA spectator ion with no bond to copperDA reducing agent that lowers copper's oxidation state
Which reactant runs out first? Stoichiometry lets you convert between mass, moles, and mole ratios for a single reactant. Real reactions usually start with TWO reactants measured out independently, and they rarely arrive in exactly the rati
Chemistry
Chemistry · L3 · Limiting Reagents and Percent Yield
The oxidation ladder: alcohols → aldehydes/ketones → carboxylic acids Alcohols, aldehydes, ketones, and carboxylic acids are all connected by a single idea: oxidation state at carbon. Climbing the ladder from alcohol to acid means removing