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OpenStem
@openstem · Joined Jul 2026
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Note~480 words · 2 min
Esterification: Alcohol + Acid → Ester + Water You've already met the alcohol group (–OH) and the carboxylic acid group (–COOH). Put an alcohol and a carboxylic acid together — usually with an acid catalyst such as concentrated sulfuric aci
Chemistry · L3 · Esters — Formation and Uses
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Chemistry · L3 · Esters — Formation and UsesNote~775 words · 4 min
What Is Electronegativity? Electronegativity is a measure of how strongly an atom pulls the pair of electrons it shares in a covalent bond toward itself. Every bonded atom has some pull on the shared pair — electronegativity just says how s
Chemistry · L3 · Electronegativity and Bond Polarity
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Chemistry · L3 · Electronegativity and Bond PolarityNote~628 words · 3 min
Catalysts in industry: a gallery beyond Haber and Contact You've already seen iron and vanadium(V) oxide as industrial catalysts — iron in the Haber process, vanadium(V) oxide in the Contact process. A catalyst still means the same thing ev
Chemistry · L3 · Catalysts in Industry
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Chemistry · L3 · Catalysts in IndustryNote~595 words · 3 min
Common Polyatomic Ions and Their Charges A polyatomic ion is a small group of atoms bonded together that carries one overall charge and behaves as a single unit when building a formula — it gets crossed, subscripted, and bracketed exactly l
Chemistry · L3 · Naming and Writing Ionic Formulae
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Chemistry · L3 · Naming and Writing Ionic FormulaeNote~586 words · 3 min
Retention Factor: Putting a Number on Chromatography Earlier you saw that dyes spread out on wet paper because they travel at different speeds — some further, some barely at all. The retention factor, Rf, turns that qualitative spreading in
Chemistry · L3 · Chromatography and Rf Values
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Chemistry · L3 · Chromatography and Rf ValuesNote~813 words · 4 min
Combustion Analysis: Measuring a Formula by Burning It You already know how to write a balanced complete-combustion equation for a hydrocarbon given its formula, and how to turn a GIVEN percent composition into an empirical formula. Combust
Chemistry · L3 · Combustion Analysis
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Chemistry · L3 · Combustion AnalysisNote~823 words · 4 min
Specific latent heat: the energy behind a phase change q = mcΔT measures heat that changes a substance's temperature within one state — heating liquid water from 20 °C to 80 °C, for example. But when a substance actually changes state — mel
Chemistry · L3 · Specific Latent Heat
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Chemistry · L3 · Specific Latent HeatNote~437 words · 2 min
A titration that isn't about pH at all An acid–base titration tracks proton transfer, and its endpoint is flagged by a pH indicator. A REDOX titration swaps both of those out: the titrant and analyte react by transferring electrons, not pro
Chemistry · L3 · Redox Titrations
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Chemistry · L3 · Redox TitrationsNote~492 words · 2 min
Organic reaction mechanisms: nucleophiles, electrophiles, and arrow pushing A reaction mechanism is a step-by-step account of how bonds break and form during a chemical reaction. Each elementary step is represented by curved arrows that sho
Chemistry · L4 · Organic reaction mechanisms: nucleophiles, electrophiles, and arrow pushing
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Chemistry · L4 · Organic reaction mechanisms: nucleophiles, electrophiles, and arrow pushingNote~431 words · 2 min
Acid–base equilibria: pH, buffers, and Ka Acid–base chemistry governs a vast range of biological, industrial, and environmental processes. Two complementary definitions frame the subject: Brønsted–Lowry (proton transfer) and Lewis (electron
Chemistry · L4 · Acid–base equilibria: pH, buffers, and Ka
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Chemistry · L4 · Acid–base equilibria: pH, buffers, and KaNote~396 words · 2 min
Thermochemistry: enthalpy, entropy, and free energy Thermochemistry investigates the heat changes that accompany chemical reactions. The three central quantities — enthalpy (H), entropy (S), and Gibbs free energy (G) — together determine wh
Chemistry · L4 · Thermochemistry: enthalpy, entropy, and free energy
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Chemistry · L4 · Thermochemistry: enthalpy, entropy, and free energyNote~411 words · 2 min
Chemical kinetics: rate laws, activation energy, and catalysis Chemical kinetics studies how fast reactions occur and what factors govern reaction rate. Kinetics is distinct from thermodynamics: a reaction can be thermodynamically spontaneo
Chemistry · L4 · Chemical kinetics: rate laws, activation energy, and catalysis
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Chemistry · L4 · Chemical kinetics: rate laws, activation energy, and catalysisNote~698 words · 3 min
Electrochemistry: standard potentials, the Nernst equation, and cell types The earlier introduction to redox covered the qualitative picture: OIL RIG, spotting which species is oxidised and which is reduced, and how a galvanic cell wires th
Chemistry · L4 · Electrochemistry: standard potentials, the Nernst equation, and cell types
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Chemistry · L4 · Electrochemistry: standard potentials, the Nernst equation, and cell typesNote~539 words · 3 min
Coordination complexes: ligands, naming, and why they're colored A coordination complex has a central transition metal ion surrounded by ligands — molecules or ions that each donate a lone electron pair to the metal, forming a coordinate (d
Chemistry · L4 · Coordination complexes: ligands, naming, and why they're colored
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Chemistry · L4 · Coordination complexes: ligands, naming, and why they're coloredNote~753 words · 4 min
Colligative Properties (Quantitative) The L3 treatment of colligative properties is purely qualitative: dissolved particles 'get in the way' of the solvent, so freezing point drops, boiling point rises, and evaporation slows. That intuition
Chemistry · L4 · Colligative Properties (Quantitative)
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Chemistry · L4 · Colligative Properties (Quantitative)Note~683 words · 3 min
Solubility equilibria: Ksp, the common ion effect, and precipitation Many ionic compounds are only sparingly soluble in water: a small amount dissolves, and the rest remains as undissolved solid in equilibrium with its dissolved ions. This
Chemistry · L4 · Solubility Equilibria: Ksp, common ion effect, and precipitation
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Chemistry · L4 · Solubility Equilibria: Ksp, common ion effect, and precipitationNote~892 words · 4 min
Intermolecular forces & molecular polarity — vectors, polarizability, and boiling-point trends London dispersion, dipole-dipole, and hydrogen bonding explain WHICH forces act between molecules. This note goes one step further and asks HOW S
Chemistry · L4 · Intermolecular forces & molecular polarity — vectors, polarizability, and boiling-point trends
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Chemistry · L4 · Intermolecular forces & molecular polarity — vectors, polarizability, and boiling-point trendsNote~594 words · 3 min
The oxidation ladder: alcohols → aldehydes/ketones → carboxylic acids Alcohols, aldehydes, ketones, and carboxylic acids are all connected by a single idea: oxidation state at carbon. Climbing the ladder from alcohol to acid means removing
Chemistry · L4 · The oxidation ladder: alcohols → aldehydes/ketones → carboxylic acids
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Chemistry · L4 · The oxidation ladder: alcohols → aldehydes/ketones → carboxylic acidsNote~700 words · 4 min
Aromatic Chemistry & Electrophilic Aromatic Substitution Benzene looks, on paper, like it should behave as three alkenes stitched into a ring — reactive C=C bonds ready to add bromine or hydrogen the way any alkene would. It doesn't. Benzen
Chemistry · L4 · Aromatic Chemistry & Electrophilic Aromatic Substitution
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Chemistry · L4 · Aromatic Chemistry & Electrophilic Aromatic SubstitutionNote~846 words · 4 min
Stereochemistry: Chirality, Enantiomers, and R/S Naming Two molecules can share exactly the same atoms, connected in exactly the same order, and still be different compounds — differing only in how their atoms are arranged in three-dimensio
Chemistry · L4 · Stereochemistry: Chirality, Enantiomers, and R/S Naming
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Chemistry · L4 · Stereochemistry: Chirality, Enantiomers, and R/S NamingNote~1157 words · 6 min
Nuclear Chemistry: The Decay Law, Mass Defect & Binding Energy At L3 you saw radioactive decay as a halving staircase — after each half-life, whatever is left gets cut in half again. That picture is correct but incomplete: it only gives cle
Chemistry · L4 · Nuclear Chemistry: The Decay Law, Mass Defect & Binding Energy
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Chemistry · L4 · Nuclear Chemistry: The Decay Law, Mass Defect & Binding EnergyNote~996 words · 5 min
Solid state chemistry: crystal classes and unit cells Most solids we handle are crystalline: their particles pack into an ordered, repeating three-dimensional pattern rather than sitting in random disorder. What holds a particular solid tog
Chemistry · L4 · Solid state chemistry: crystal classes and unit cells
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Chemistry · L4 · Solid state chemistry: crystal classes and unit cellsNote~548 words · 3 min
Spectroscopy basics: what each technique measures Spectroscopy is a family of techniques built on one idea: shine a form of energy at a sample and see what happens to it. What gets absorbed, transmitted, or emitted depends on the sample's s
Chemistry · L4 · Spectroscopy basics: what each technique measures
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Chemistry · L4 · Spectroscopy basics: what each technique measuresNote~855 words · 4 min
Gibbs free energy: the four cases, the crossover point, and the road to K This note assumes you already have ΔG = ΔH − TΔS and the idea that ΔG < 0 means spontaneous. Here we go further: work through the reasoning behind all four ΔH/ΔS sign
Chemistry · L4 · Gibbs free energy: the four cases, the crossover point, and the road to K
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Chemistry · L4 · Gibbs free energy: the four cases, the crossover point, and the road to KNote~1002 words · 5 min
Classifying polymers by thermal and mechanical behavior L3 covered HOW polymer chains get built — addition versus condensation. This note asks a different question: once a chain exists, how does the material actually BEHAVE when you heat it
Chemistry · L4 · Classifying Polymers by Thermal & Mechanical Behavior
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Chemistry · L4 · Classifying Polymers by Thermal & Mechanical BehaviorNote~680 words · 3 min
From amino acids to protein structure — a chemist's view A protein is, chemically, a long chain built from a small alphabet of monomers — the 20 standard amino acids — joined end to end by a single repeating bond type. Understanding a prote
Chemistry · L4 · From amino acids to protein structure — a chemist's view
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Chemistry · L4 · From amino acids to protein structure — a chemist's viewNote~627 words · 3 min
Real Gases & the Ideal Gas Law Boyle's law, Charles's law, and Avogadro's law each describe how two of a gas's variables relate while the others are held fixed. Combine all three and you get one master equation that handles any two states o
Chemistry · L4 · Real Gases & the Ideal Gas Law
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Chemistry · L4 · Real Gases & the Ideal Gas LawNote~741 words · 4 min
Catalysis and green chemistry: lowering barriers, cutting waste A catalyst speeds up a reaction by opening an alternate pathway with a lower activation energy (Ea), without being consumed overall — it may take part in an intermediate step,
Chemistry · L4 · Catalysis and green chemistry: lowering barriers, cutting waste
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Chemistry · L4 · Catalysis and green chemistry: lowering barriers, cutting wasteNote~647 words · 3 min
Transition metal chemistry in solution: colors, amphoterism, and trends Beyond the coordination chemistry of ligands and geometry, transition metals show a set of characteristic descriptive behaviors in aqueous solution: distinctive aqua-io
Chemistry · L4 · Transition metal chemistry in solution: colors, amphoterism, and trends
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Chemistry · L4 · Transition metal chemistry in solution: colors, amphoterism, and trendsNote~957 words · 5 min
Polyprotic acids: stepwise dissociation, successive Ka values, and multi-equivalence-point titrations A polyprotic acid loses more than one proton, but it does so one proton at a time, through a series of distinct equilibria — each with its
Chemistry · L4 · Polyprotic acids: stepwise dissociation, successive Ka values, and multi-equivalence-point titrations
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Chemistry · L4 · Polyprotic acids: stepwise dissociation, successive Ka values, and multi-equivalence-point titrations