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Chemistry · L5 · Asymmetric Catalysis Mechanisms: The Quadrant Model, Sharpless Epoxidation, and Organocatalysis · flowchart

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by @openstemUpdated Chemistry
Chiral metal center(Rh or Ru + BINAP-typebidentate phosphine)Quadrant 1: blocked(bulky ligand aryl group)Quadrant 2: openQuadrant 3: blocked(bulky ligand aryl group)Quadrant 4: openProchiral alkene substrate canonly approach through the open quadrantsMigratory insertion delivers Hto the one face presented to the metalSingle enantiomer of producthigh ee

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