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Chemistry · L5 · Glass Transition, Crystallinity & Chain-Structure–Property Control · flowchart

Chemistry
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Chain structurePacking route orflexibility route?How regular isthe chain packing?High crystallinity XcLow crystallinity XcHow easily doesthe backbone rotate?High TgLow TgStiffer, denser,more opaque, more brittleMore flexible,clearer, lower densityRigid glass persiststo higher temperatureRubbery / softnear room temperatureLinear vs branchedLinear, regularBranched, irregularBackbone flexibilityBulky / rigid side groupsFlexible backbone
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