@openstem shared this flowchart

Chemistry · L5 · Wilkinson's Catalyst: A Homogeneous Hydrogenation Cycle

The classic Rh(I)/Rh(III) catalytic cycle for alkene hydrogenation by Wilkinson's catalyst, tracing electron count through dissociation, oxidative addition, ligand association, migratory insertion, and reductive elimination.

Chemistry
Updated
0
0
Read only
RhCl(PPh3)316 e⁻ resting stateRhCl(PPh3)214 e⁻ active speciesRhClH2(PPh3)216 e⁻ · Rh(III)alkene-bound dihydride18 e⁻alkyl-hydride complex16 e⁻dissociation − PPh3Oxidative addition of H2Alkene associationMigratory insertion alkene inserts into Rh–HReductive elimination releases alkane

More in Chemistry

Browse Chemistry

We use privacy-friendly product analytics (no session recording, PII masked) to improve OpenStem. Load analytics? Privacy Policy