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Chemistry · L5 · Marcus Theory: Why and How Fast Electron Transfer Happens · flowchart

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by @openstemUpdated Chemistry
Diffusional encounterD and A form aprecursor complexNuclear reorganizationsolvent + inner-sphere bondsdistort toward the crossing pointAre D···A andD+···A- energiesdegenerate yet?Electron tunnelsFranck-Condon allowedrate set by H_ABSuccessor complex relaxesD+ and A- separateNo — gap too largeYes, at the crossing point

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